You are here: Home
/ Publication Information
Title: Alkaline peroxide treatment of ECF bleached softwood kraft pulps. Part 1. characterizing the effect of alkaline peroxide treatment on carboxyl groups of fibers
Author: Dang, Zheng; Elder, Thomas; Ragauskas, Arthur J.
Source: Holzforschung, Vol. 61: 445-450
Description: The influence of alkaline peroxide treatment has been characterized on elementally chlorine-free (ECF) bleached softwood (SW) kraft pulp. The results indicate that fiber charge increased with an increase in peroxide charge: a maximum fiber charge increment of 16.6% was obtained with 8.0% more peroxide charge on oven-dried (0.d.) pulp at 60.0°C. Two primary bleaching temperatures of 60.0°C and 90.0°C were investigated during peroxide treatment. Copper number decreased for peroxide charges of 0.5% and 1.O% at 60.0°C and 90.0°C, respectively, then increased with increasing peroxide charge. Both fiber charge and copper number approached constant values when 4.0% or higher peroxide charge was applied. Peroxide treatment on a bleached kraft pulp at 90.0eC resulted in lower fiber charge and lower intrinsic viscosity compared to treatment at 60.0°C. Sodium borohydride (NaBH4) pretreatment was able to protect the fibers from being degraded during peroxide bleaching. Fiber charge and copper number were compared after peroxide treatment of ECF bleached kraft pulp to NaBH4-reduced ECF bleached kraft pulp. The results indicate that the carbonyl group content of fibers is favorable for improving fiber charge after peroxide treatment.
View or Print this Publication (1.16 MB bytes)
- We recommend that you also print this page and attach it to the printout of the article, to retain the full citation information.
- This article was written and prepared by U.S. Government employees on official time, and is therefore in the public domain.
Dang, Zheng; Elder, Thomas; Ragauskas, Arthur J. 2007. Alkaline peroxide treatment of ECF bleached softwood kraft pulps. Part 1. characterizing the effect of alkaline peroxide treatment on carboxyl groups of fibers. Holzforschung, Vol. 61: 445-450
Get the latest version of the Adobe Acrobat reader or Acrobat Reader for Windows with Search and Accessibility